Mineralogy and geochemistry of soils developed along the slopes of Mt. Cameroon, West Africa
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Author list: Manga VE, Suh CE, Agyingi CM, Shemang EM
Publisher: Elsevier
Place: OXFORD
Publication year: 2013
Journal: Journal of African Earth Sciences (1464-343X)
Journal acronym: J AFR EARTH SCI
Volume number: 81
Start page: 82
End page: 93
Number of pages: 12
ISSN: 1464-343X
Languages: English-Great Britain (EN-GB)
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Abstract
Changes in soil mineralogy and geochemistry are investigated in four soil profiles developed from rocks of unknown ages on an elevational gradient on the lower slopes of Mt. Cameroon. The study objectives include evaluation of weathering intensities of the profiles using proxies of weathering, description of mineralogy and major element geochemistry. Methods of study include major element analysis for <2 mm fraction by ICP-AES, quantification of secondary Fe and Al phases by extractive dissolution and determination of soil mineralogy by semi quantitative XRD. BUA, the most weathered profile is located at the highest elevation while the moderately weathered profiles (MUT and LBE) are located in lower elevations with higher rainfall. Soil pH((H2O)) is highest in the most weathered profile which equally exhibits the lowest Sigma bases and base saturation. Secondary extractible aluminum (Al-d) followed by organic matter content explains the greatest amount of soil pH variation. The distribution of iron (Fe) components (i.e. dithionite-citrate extractible, Fe-d; amorphous Fe-o; and total, Fe-T) are controlled by the differential dissolution of Fe-bearing minerals and Fe-mobility at low and high altitudes. Consequently, the ratio Fe-d/Fe-T can serve as a useful indicator of weathering intensity under different climatic conditions. Al and Ti display the least relative mobility; however, Ti is comparatively more mobile especially in the low elevation sites. (C) 2013 Elsevier Ltd. All rights reserved.
Keywords
Mineralogy, Mt. Cameroon, Soil geochemistry, weathering
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